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How to run a sustainability science research group sustainably?
(2020-08-25)
Rigorous sustainability science includes addressing pressing real-world problems, weaving multiple knowledge systems, and striving for transformative change. However, these key attributes of sustainability science often conflict with university structures and established academic work practices, for instance with regard to frequent long-distance travel. Such contradictions between key principles of sustainability and everyday practices are experienced by many researchers not only at university level, but also in their ...
Aufsatz
Environmental and Economic Performance of CO₂-Based Methanol Production Using Long-Distance Transport for H₂ in Combination with CO₂ Point Sources: A Case Study for Germany
(2022-03-29)
The use of CO₂-based hydrocarbons plays a crucial role in reducing the climate footprint for several industry sectors, such as the chemical industry. Recent studies showed that regions which are favorable for the production of CO₂-based hydrocarbons from an energy perspective often do not provide concentrated point sources for CO₂, which leads to an increased environmental impact due to the higher energy demand of direct air capture processes. Thus, producing H2 in regions with high renewable power potential and ...
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The SARS-CoV-2 spike protein is vulnerable to moderate electric fields
(2021-09-13)
Most of the ongoing projects aimed at the development of specific therapies and vaccines against COVID-19 use the SARS-CoV-2 spike (S) protein as the main target. The binding of the spike protein with the ACE2 receptor (ACE2) of the host cell constitutes the first and key step for virus entry. During this process, the receptor binding domain (RBD) of the S protein plays an essential role, since it contains the receptor binding motif (RBM), responsible for the docking to the receptor. So far, mostly biochemical methods ...
Aufsatz
Multiscale modeling of ferroelectrics with stochastic grain size distribution
(2021-12-20)
Macroscopic properties of ferroelectrics are controlled by processes on the microscale, in particular the switching of crystal unit cells and the movement of domain walls, respectively. Besides these microscopic levels, the grains of a polycrystalline material constitute the mesoscopic scale. Interactions of grains with statistically distributed orientations, as a consequence of mechanical and electrostatic mismatch, give rise to for example, residual stress which in turn affects domain switching. A multiscale modeling ...
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Land cover transitions and effects of transhumance on available forage biomass of rangelands in Benin
(2021-11-30)
This study examined the effects of transhumance pressure on total abavoe-ground biomass and forage availability on rangelands in Benin. We also investigated the implications of land cover transitions on rangelands over a 31-year period. Our work was carried out in three regions of Benin representing distinct phytogeographic regimes: Ketou, Tchaourou, and Sinende. Ground-truthing and biomass sampling of the herbaceous and phanaerophyte strata were carried out between the 2016 peak vegetation period and the onset of ...
Aufsatz
Evaluation of Statistical-Downscaling/Bias-Correction Methods to Predict Hydrologic Responses to Climate Change in the Zarrine River Basin, Iran
(2018-04-20)
Modeling the hydrologic responses to future changes of climate is important for improving adaptive water management. In the present application to the Zarrine River Basin (ZRB), with the major reach being the main inflow source of Lake Urmia (LU), firstly future daily temperatures and precipitation are predicted using two statistical downscaling methods: the classical statistical downscaling model (SDSM), augmented by a trend-preserving bias correction, and a two-step updated quantile mapping (QM) method. The general ...
Aufsatz
Coinage Metal Complexes of the Carbenic Tautomer of a Conjugated Mesomeric Betaine Akin to Nitron
(2017-07-07)
This study was motivated by our recent observation that the analytical reagent Nitron (2) is an “instant carbene”, whose reaction with coinage metal salts MX afforded complexes of its carbenic tautomer 1,4-diphenyl-3-phenylamino-1,2,4-triazol-5-ylidene (2′). Our aim was to establish an alkyl homologue of 2 in order to achieve a carbenic tautomer of higher donicity. For this purpose 1-tert-butyl-4-methyl-1,2,4-triazol-4-ium-3-tert-butylaminide (6) was synthesized. Its reactions with MX afforded complexes of the carbenic ...
Aufsatz
Circular Dichroism in Fluorescence Emission Following the C 1s→π* Excitation and Resonant Auger Decay of Carbon Monoxide
(2018-06-26)
Dichroism in angle-resolved spectra of circularly polarized fluorescence from freely-rotating CO molecules was studied experimentally and theoretically. For this purpose, carbon monoxide in the gas phase was exposed to circularly polarized soft X-ray synchrotron radiation. The photon energy was tuned across the C 1s→π* resonant excitation, which decayed via the participator Auger transition into the CO+ A 2Π state. The dichroic parameter β1 of the subsequent CO+ (A 2Π → X 2Σ+) visible fluorescence was measured by ...
Aufsatz
Rainfall Prediction with AMSR–E Soil Moisture Products Using SM2RAIN and Nonlinear Autoregressive Networks with Exogenous Input (NARX) for Poorly Gauged Basins: Application to the Karkheh River Basin, Iran
(2018-07-23)
Accurate estimates of daily rainfall are essential for understanding and modeling the physical processes involved in the interaction between the land surface and the atmosphere. In this study, daily satellite soil moisture observations from the Advanced Microwave Scanning Radiometer–Earth Observing System (AMSR–E) generated by implementing the standard National Aeronautics and Space Administration (NASA) algorithm are employed for estimating rainfall, firstly, through the use of recently developed approach, SM2RAIN ...
Aufsatz
Extreme Ultraviolet to Visible Dispersed Single Photon Detection for Highly Sensitive Sensing of Fundamental Processes in Diverse Samples
(2018-05-23)
The detection of a single photon is the most sensitive method for sensing of photon emission. A common technique for single photon detection uses microchannel plate arrays combined with photocathodes and position sensitive anodes. Here, we report on the combination of such detectors with grating diffraction spectrometers, constituting a low-noise wavelength resolving photon spectroscopy apparatus with versatile applicability. We recapitulate the operation principle of such detectors and present the details of the ...