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Aufsatz
Bis‐[3]Ferrocenophanes with Central >E−E’< Bonds (E, E’=P, SiH): Preparation, Properties, and Thermal Activation
(2019-06-26)
A series of bis‐[3]ferrocenophanes of the general type Fe(C5H4E’)2E−E(E'C5H4)2Fe (E=P, SiH and E’=PtBu, NneoPentyl, NSi(CH3)3) with an isolobal molecular framework have been prepared and characterized by heteronuclear NMR spectroscopy and X‐ray crystallography. The thermal dissociation behavior with respect to homolytic fission of the central bond generating phosphorus centered radicals was investigated using EPR spectroscopy and quantum chemical calculations.
Aufsatz
Socio-Economic Viability of Urban Agriculture - A Comparative Analysis of Success Factors in Germany
(2019-04-04)
Socio-economic viability of urban agriculture (UA) is, especially regarding non-commercially oriented initiatives, at most a generically treated issue in scientific literature. Given a lack of data on yields, labor input, or saved expenditures, only a few studies have described it either from a cost-avoidance or a specific benefit generation perspective. Our hypothesis is that hybrid roles of consumers and producers in urban agriculture challenge the appraisal of socio-economic viability. This paper presents an ...
Aufsatz
Distributed Learning in the Classroom: Effects of Rereading Schedules Depend on Time of Test
(2019-01-09)
Research with adults in laboratory settings has shown that distributed rereading is a beneficial learning strategy but its effects depend on time of test. When learning outcomes are measured immediately after rereading, distributed rereading yields no benefits or even detrimental effects on learning, but the beneficial effects emerge two days later. In a preregistered experiment, the effects of distributed rereading were investigated in a classroom setting with school students. Seventh-graders (N = 191) reread a text ...
Aufsatz
Quantum optimal control of the dissipative production of a maximally entangled state
(2018-12-14)
Entanglement generation can be robust against certain types of noise in approaches that deliberately incorporate dissipation into the system dynamics. The presence of additional dissipation channels may, however, limit fidelity and speed of the process. Here we show how quantum optimal control techniques can be used to both speed up the entanglement generation and increase the fidelity in a realistic setup, whilst respecting typical experimental limitations. For the example of entangling two trapped ion qubits (Lin ...
Aufsatz
Metallated [3]Ferrocenophanes Containing P3M Bridges (M = Li, Na, K)
(2018-07-11)
Alkali-metal phosphanides can be embedded into a [3]ferrocenophane scaffold giving rise to bicyclic ferrocenophanes [MFe(C5H4PtBu)2P] (M = Li, Na, K). Coordination of the alkali-metal ions takes place via the terminal phosphorus atoms adopting a puckered P3M four-membered ring. All compounds were characterized via single-crystal X-ray diffraction and multinuclear NMR spectroscopy (1H, 31P, 7Li), whereas 13C NMR data could only be recorded for the Li derivative, owing to the limited solubility of its heavier congeners ...
Aufsatz
Aqueous Leaching Prior to Dewatering Improves the Quality of Solid Fuels from Grasslands
(2018-04-04)
Renewable energies are necessary to reduce greenhouse gas emissions in energy production, and biomass plays a dominant role in the renewable energy sector. Combustion of biomass constitutes an efficient conversion technique, but is hindered by harmful elements which are frequently contained in residual grassland biomass. We investigated the effect of leaching on solid fuel quality with three independent experiments including the following treatments: (1) with or without leaching, (2) with leaching at various water ...
Aufsatz
Synthesis and crystal structure of μ-[1,1′-di(mesitylphosphanido)ferrocene]bis[η5-cyclopentadienylnickel(II)] tetrahydrofurane solvate, C42H48FeNi2OP2
(2018-03-08)
C42H48FeNi2OP2, orthorhombic, Pbca (no. 61), a = 9.4551(4) Å, b = 19.7133(9) Å, c = 39.693(2) Å, V = 7398.4(6) Å3, Z = 8, Rgt(F) = 0.0598, wRref(F2) = 0.1481, T = 100(2) K.
Aufsatz
Farmers’ Perception of Water Quality and Risks in the Mashavera River Basin, Georgia: Analyzing the Vulnerability of the Social-Ecological System through Community Perceptions
(2018-08-28)
Competing natural resources usage that leads to dramatic land use changes can threaten the balance of a social-ecological system. When this is the case, communities are directly exposed to the negative consequences of those land use changes. The Mashavera River Basin is considered one of the hotspots of environmental pollution in Georgia. This is of importance for public health because the food production from this basin meets a substantial proportion of the country’s food demand. The farmers’ perception of the water ...
Aufsatz
Evolution of Rural Livelihood Strategies in a Remote Sino-Mongolian Border Area: A Cross-Country Analysis
(2018-03-29)
Ecologically sound natural resources management is still the backbone of rural livelihoods in many regions of the world. The Altai-Dzungarian region between China and Mongolia constitutes an ideal site to study how political, economic, infrastructural, and cultural differences affect rural livelihoods. Structured semi-quantitative interviews were conducted with 483 households on both sides to characterise their current livelihood strategies and assess the importance of the various activities for the households’ current ...
Aufsatz
Participatory Mapping as an Approach to Identify Grazing Pressure in the Altay Mountains, Mongolia
(2018-06-11)
Sustainable rangeland management is crucial for maintaining forage resources in pastoral systems, globally. However, pastoral regions are often remote and therefore data poor when it comes to resource monitoring. We tested participatory mapping as a means to rapidly assess rangeland use to identify areas with high grazing pressure. Participatory geographic information system data and herbaceous biomass production data were collected and georeferenced to establish a grazing pressure index for a summer pasture in the ...