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Now showing items 11-20 of 26
Aufsatz
Preparation and Molecular Structure of a Cyclopentyl-Substituted Cage Hexasilsesquioxane T6 (T = cyclopentyl-SiO1.5) Starting from the Corresponding Silanetriol
(2017-10-04)
Cyclopentyl substituted silanetriol can be prepared and isolated. Its condensation yields the corresponding disiloxanetetrol as a primary condensation product. Further condensation leads to the hexameric polyhedral silsesquioxane cage T6. The latter has been mentioned in the literature before however, lacking structural data. All compounds have been characterized with multinuclear NMR spectroscopy and, in addition, the molecular structures have been determined in the case of the disiloxanetetrol and the hexasilsesquioxane ...
Aufsatz
The Impact of Visualizing Nested Sets. An Empirical Study on Tree Diagrams and Unit Squares
(2017-01-06)
It is an ongoing debate, what properties of visualizations increase people’s performance when solving Bayesian reasoning tasks. In the discussion of the properties of two visualizations, i.e., the tree diagram and the unit square, we emphasize how both visualizations make relevant subset relations transparent. Actually, the unit square with natural frequencies reveals the subset relation that is essential for the Bayes’ rule in a numerical and geometrical way whereas the tree diagram with natural frequencies does it ...
Aufsatz
Beating the limits with initial correlations
(2017-11-28)
Fast and reliable reset of a qubit is a key prerequisite for any quantum technology. For real world open quantum systems undergoing non-Markovian dynamics, reset implies not only purification, but in particular erasure of initial correlations between qubit and environment. Here, we derive optimal reset protocols using a combination of geometric and numerical control theory. For factorizing initial states, we find a lower limit for the entropy reduction of the qubit as well as a speed limit. The time-optimal solution ...
Aufsatz
Coinage Metal Complexes of the Carbenic Tautomer of a Conjugated Mesomeric Betaine Akin to Nitron
(2017-07-07)
This study was motivated by our recent observation that the analytical reagent Nitron (2) is an “instant carbene”, whose reaction with coinage metal salts MX afforded complexes of its carbenic tautomer 1,4-diphenyl-3-phenylamino-1,2,4-triazol-5-ylidene (2′). Our aim was to establish an alkyl homologue of 2 in order to achieve a carbenic tautomer of higher donicity. For this purpose 1-tert-butyl-4-methyl-1,2,4-triazol-4-ium-3-tert-butylaminide (6) was synthesized. Its reactions with MX afforded complexes of the carbenic ...
Aufsatz
Fat-containing cells are eliminated during Dictyostelium development
(2017-09-15)
Triacylglycerol is a universal storage molecule for metabolic energy in living organisms. However, Dictyostelium amoebae, that have accumulated storage fat from added fatty acids do not progress through the starvation period preceding the development of the durable spore. Mutants deficient in genes of fat metabolism, such as fcsA, encoding a fatty acid activating enzyme, or dgat1 and dgat2, specifying proteins that synthesize triacylglycerol, strongly increase their chances to contribute to the spore fraction of the ...
Dissertation
Lipid Droplets und assoziierte Proteine im Wachstum und der multizellulären Entwicklung von Dictyostelium discoideum
(2017-12-15)
Zusammenfassung:
Lipid Droplets (LDs) und damit assoziierte Proteine wurden bisher in D. discoideum ausschließlich in dem einzelligen, vegetativen Stadium untersucht. Die Ergebnisse der vorliegenden Arbeit zeigen deren Einfluss auf die multizelluläre Entwicklung. Statt in der Hungerphase einen Vorteil durch gespeicherte Fettreserven zu vermitteln, stirbt ein Großteil der fetten Zellen in der Entwicklung. Im Mischexperiment, in dem unbehandelten Zellen mit LD-tragenden Zellen kompetieren, stellen letztere nur 10 % ...
Dissertation
Optimierung von Nanostrukturen in Dielektrika für biomedizinische und technische Applikationen durch zeitlich geformte Femtosekunden-Laserpulse
(2017-09-28)
Das Ablationsverhalten von Dielektrika wird in Abhängigkeit von unterschiedlich zeitlich geformten Femtosekunden-Laserpulsen analysiert. Dabei entstehen unterschiedlich tiefe Strukturen im Nano- und Mikrometerbereich. In zwei Anwendungsbeispielen wird deren Anwendbarkeit für biomedizinische und technische Applikationen beschrieben.
Preprint
A free boundary approach to the Rosensweig instability of ferrofluids
(2017-04-18)
We establish the existence of saddle points for a free boundary problem describing the two-dimensional free surface of a ferrofluid which undergoes normal field instability (also known as Rosensweig instability). The starting point consists in the ferro-hydrostatic equations for the magnetic potentials in the ferrofluid and air, and the function describing their interface. The former constitute the strong form for the Euler-Lagrange equations of a convex-concave functional. We extend this functional in order to ...
Dissertation
Computing Quot Schemes
(2017-02-27)
The main goal of this thesis is to develop computational methods which allow effective computations on Hilbert and Quot schemes. At first we introduce marked bases over modules. They may be considered as a form of Gröbner basis which do not depend on a term order. Instead, one chooses for each generator some term as head module term such that the head module terms generate a prescribed monomial module. We show that the involutive normal form algorithm with respect to Pommaret division will terminate if the prescribed ...