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Aufsatz
Theory for the optical properties of small Hg_n clusters
(1991)
The static and dynamical polarizabilities of the Hg-dimer are calculated by using a Hubbard Hamiltonian to describe the electronic structure. The Hamiltonian is diagonalized exactly within a subspace of second-quantized electronic states from which only multiply ionized atomic configurations have been excluded. With this approximation we can describe the most important electronic transitions including the effect of charge fluctuations. We analyze the polarizability as a function of the intraatomic Coulomb interaction ...
Aufsatz
Time-resolved studies of neutral and ionized Na_n clusters with femtosecond light pulses
(1993)
The real-time dynamics of Na_n (n=3-21) cluster multiphoton ionization and fragmentation has been studied in beam experiments applying femtosecond pump-probe techniques in combination with ion and electron spectroscopy. Three dimensional wave packet motions in the trimer Na_3 ground state X and excited state B have been observed. We report the first study of cluster properties (energy, bandwidth and lifetime of intermediate resonances Na_n^*) with femtosecond laser pulses. The observation of four absorption resonances ...
Aufsatz
Femtosecond dynamics of molecular and cluster ionization and fragmentation
(1993)
The real-time dynamics of molecular (Na_2 . Na_3) and cluster Na_n (n=4-2l) multiphoton ionization and -fragmentation has been studied in beam experiments applying femtosecond pump-probe techniques in combination with ion and electron spectroscopy. Wave packet motion in the dimer Na_2 reveals two independent multiphoton ionization processes while the higher dimensional motion in the trimer Na_3 reflects the chaotic vibrational motion in this floppy system. The first studies of cluster properties (energy, bandwidth ...
Aufsatz
Theory for the change of bond character in divalent-metal clusters
(1991)
To determine the size dependence of the bonding in divalent-metal clusters we use a many-electron Hamiltonian describing the interplay between van der Waals (vdW) and covalent interactions. Using a saddle-point slave-boson method and taking into account the size-dependent screening of charge fluctuations, we obtain for Hg_n a sharp transition from vdW to covalent bonding for increasing n. We show also, by solving the model Hamiltonian exactly, that for divalent metals vdW and covalent bonding coexist already in the dimers.
Aufsatz
Sulfur transfer and activation by ubiquitin-like modifier system Uba4•Urm1 link protein urmylation and tRNA thiolation in yeast
(2016-10-24)
Urm1 is a unique dual-function member of the ubiquitin protein family and conserved from yeast to man. It acts both as a protein modifier in ubiquitin-like urmylation and as a sulfur donor for tRNA thiolation, which in concert with the Elongator pathway forms 5-methoxy-carbonyl-methyl-2-thio (mcm5s2) modified wobble uridines (U34) in anticodons. Using Saccharomyces cerevisiae as a model to study a relationship between these two functions, we examined whether cultivation temperature and sulfur supply previously ...
Aufsatz
Die Masse macht's!
(GIT VERLAG GmbH & Co. KG - A Wiley Company, 2008-09)
Die biochemische Beschreibung funktioneller Proteininteraktionsnetzwerke hat in den letzten Jahren einen starken Wandel erfahren. Mittels hochauflösender biologischer Massenspektrometrie(MS) ist es möglich Netzwerkkomponenten, wie Proteine schnell und zuverlässig zu identifizieren und auf ihre Modifikationen hin zu untersuchen.
Innerhalb des Promotionskollegs (PK) Proteomics der Universität Kassel bietet die MS neue Ansatzpunkte für die Beantwortung molekularbiologischer Fragestellungen und liefert Ergänzungen zu ...
Aufsatz
Quenching of High Entropy Alloys after Annealing
(2020)
The effect of cooling rate after annealing at 900 °C on the microstructure and hardness of high entropy alloys was investigated using two typical samples with the chemical composition of Co₁₆Cr₁₄.₅Fe₂₉Mn₁₁.₅Ni₂₉ and Co₁₁.₅Cr₇Fe₂₇Mn₂₇Ni₂₇(Nb₀.₀₈C₀.₅) (at%). The microstructural characterisation and hardness measurements were carried out by optical microscopy, scanning electron microscopy, wavelength-dispersive X-ray spectroscopy, electron back scattered diffraction, X-ray diffraction technique and Vickers hardness ...
Aufsatz
Are farmer perceptions among significant determinants of adoption of agricultural diversity in Malawi? A case of Lilongwe district
(2020-12-14)
Agricultural diversity can strengthen resilience of livelihood of farmers to climate change and market uncertainties while, potentially at the same time, o ering better dietary and nutritional prospects for households. Adoption of agricultural diversity in Malawi is low. Policy-makers, researchers, non-governmental organisations (NGOs), and extension staff need to understand dynamics of adoption of agricultural diversity in order to develop appropriate policies and interventions to promote agricultural diversification. ...
Aufsatz
Does interpersonal behavior of psychotherapy trainees differ in private and professional relationships?
(2015)
• Aim: The present study aimed to evaluate the effect of trainees’ interpersonal behavior on work involvement (WI) and compared their social behavior within professional and private relationships as well as between different psychotherapeutic orientations.
• Methods: The interpersonal scales of the Intrex short-form questionnaire and the Work Involvement Scale (WIS) were used to evaluate two samples of German psychotherapy trainees in psychoanalytic, psychodynamic, and cognitive behavioral therapy training. Trainees ...
Aufsatz
A value chain analysis of baobab (Adansonia digitata L.) products in Eastern and Coastal Kenya
(2019-11-14)
A growing demand for the highly nutritious baobab fruit pulp from Europe and North America raises the question whether the marketing of baobab (Adansonia digitata L.) products could be an opportunity as an income source for rural communities in Kenya, or if the increased demand from overseas would disturb domestic baobab use. To gain an idea of domestic baobab use, a value chain analysis of edible baobab products was performed, using qualitative methods. By using a non-probability sampling, 134 baobab value chain ...