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Metallated [3]Ferrocenophanes Containing P3M Bridges (M = Li, Na, K)
(2018-07-11)
Alkali-metal phosphanides can be embedded into a [3]ferrocenophane scaffold giving rise to bicyclic ferrocenophanes [MFe(C5H4PtBu)2P] (M = Li, Na, K). Coordination of the alkali-metal ions takes place via the terminal phosphorus atoms adopting a puckered P3M four-membered ring. All compounds were characterized via single-crystal X-ray diffraction and multinuclear NMR spectroscopy (1H, 31P, 7Li), whereas 13C NMR data could only be recorded for the Li derivative, owing to the limited solubility of its heavier congeners ...
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Synthesis and crystal structure of μ-[1,1′-di(mesitylphosphanido)ferrocene]bis[η5-cyclopentadienylnickel(II)] tetrahydrofurane solvate, C42H48FeNi2OP2
(2018-03-08)
C42H48FeNi2OP2, orthorhombic, Pbca (no. 61), a = 9.4551(4) Å, b = 19.7133(9) Å, c = 39.693(2) Å, V = 7398.4(6) Å3, Z = 8, Rgt(F) = 0.0598, wRref(F2) = 0.1481, T = 100(2) K.
Aufsatz
Morphological and Genetic Diversity of Sea Buckthorn (Hippophae rhamnoides L.) in the Karakoram Mountains of Northern Pakistan
(2018-07-30)
Sea buckthorn (Hippophae rhamnoides L.) is a dioecious, wind-pollinated shrub growing in Eurasia including the Karakoram Mountains of Pakistan (Gilgit-Baltistan territory). Contrary to the situation in other countries, in Pakistan this species is heavily underutilized. Moreover, a striking diversity of berry colors and shapes in Pakistan raises the question: which varieties might be more suitable for different national and international markets? Therefore, both morphological and genetic diversity of sea buckthorn ...
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Estimation of Vegetable Crop Parameter by Multi-temporal UAV-Borne Images
(2018-05-22)
3D point cloud analysis of imagery collected by unmanned aerial vehicles (UAV) has been shown to be a valuable tool for estimation of crop phenotypic traits, such as plant height, in several species. Spatial information about these phenotypic traits can be used to derive information about other important crop characteristics, like fresh biomass yield, which could not be derived directly from the point clouds. Previous approaches have often only considered single date measurements using a single point cloud derived ...
Aufsatz
Evaluation of Statistical-Downscaling/Bias-Correction Methods to Predict Hydrologic Responses to Climate Change in the Zarrine River Basin, Iran
(2018-04-20)
Modeling the hydrologic responses to future changes of climate is important for improving adaptive water management. In the present application to the Zarrine River Basin (ZRB), with the major reach being the main inflow source of Lake Urmia (LU), firstly future daily temperatures and precipitation are predicted using two statistical downscaling methods: the classical statistical downscaling model (SDSM), augmented by a trend-preserving bias correction, and a two-step updated quantile mapping (QM) method. The general ...
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Farmers’ Perception of Water Quality and Risks in the Mashavera River Basin, Georgia: Analyzing the Vulnerability of the Social-Ecological System through Community Perceptions
(2018-08-28)
Competing natural resources usage that leads to dramatic land use changes can threaten the balance of a social-ecological system. When this is the case, communities are directly exposed to the negative consequences of those land use changes. The Mashavera River Basin is considered one of the hotspots of environmental pollution in Georgia. This is of importance for public health because the food production from this basin meets a substantial proportion of the country’s food demand. The farmers’ perception of the water ...
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Evolution of Rural Livelihood Strategies in a Remote Sino-Mongolian Border Area: A Cross-Country Analysis
(2018-03-29)
Ecologically sound natural resources management is still the backbone of rural livelihoods in many regions of the world. The Altai-Dzungarian region between China and Mongolia constitutes an ideal site to study how political, economic, infrastructural, and cultural differences affect rural livelihoods. Structured semi-quantitative interviews were conducted with 483 households on both sides to characterise their current livelihood strategies and assess the importance of the various activities for the households’ current ...
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Consumer Preferences for Local Food: Testing an Extended Norm Taxonomy
(2018-04-24)
Consumer attitudes toward consuming and buying locally produced food are well studied. By contrast, the topic of consumer preferences for local food, with a special emphasis on the role of norms, still lacks empirical evidence. To study the influence of norms and morals on the intention to buy local food products, a quantitative study (N = 327) focusing on external social and internalized moral norms was conducted using the constructs of the theory of planned behavior in combination with an extended norm taxonomy and ...
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Aqueous Leaching Prior to Dewatering Improves the Quality of Solid Fuels from Grasslands
(2018-04-04)
Renewable energies are necessary to reduce greenhouse gas emissions in energy production, and biomass plays a dominant role in the renewable energy sector. Combustion of biomass constitutes an efficient conversion technique, but is hindered by harmful elements which are frequently contained in residual grassland biomass. We investigated the effect of leaching on solid fuel quality with three independent experiments including the following treatments: (1) with or without leaching, (2) with leaching at various water ...
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Short-spored Subulicystidium (Trechisporales, Basidiomycota): high morphological diversity and only partly clear species boundaries
(2018-06-27)
Diversity of corticioid fungi (resupinate Basidiomycota), especially outside the northern temperate climatic zone, remains poorly explored. Furthermore, most of the known species are delimited by morphological concepts only and, not rarely, these concepts are too broad and need to be tested by molecular tools. For many decades, the delimitation of species in the genus Subulicystidium (Hydnodontaceae, Trechisporales) was a challenge for mycologists. The presence of numerous transitional forms as to basidiospore size ...